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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
2-溴噻吩
合成路线
(共 523 条)
1003-09-4
2-溴噻吩
→
反应条件
反应条件
cesium fluoride in toluene Stille cross-coupling reaction; Heating;
参考文献
Haemmerle, Johanna; Schnuerch, Michael; Stanetty, Peter
Synlett, 2007 , # 19 p. 2975 - 2978
1003-09-4
2-溴噻吩
+
118486-94-5
2-(三丁基锡烷基)呋喃
→
反应条件
27521-80-8
2-(2-噻嗯基)呋喃
反应条件
tris(dibenzylideneacetone)dipalladium (0); P(N(CH2Ph)CH2CH2)3N; cesium fluoride in tetrahydrofuran T=50°C; Stille cross-coupling; 30 h;
参考文献
Su, Weiping; Urgaonkar, Sameer; McLaughlin, Patrick A.; Verkade, John G.
Journal of the American Chemical Society, 2004 , vol. 126, # 50 p. 16433 - 16439
1003-09-4
2-溴噻吩
+
6165-69-1
3-噻吩硼酸
→
反应条件
2404-89-9
2,3-联噻吩
反应条件
bis(η3-allyl-μ-chloropalladium(II)); N,N,N′,N′-tetra(diphenylphosphinomethyl)-1,2-ethylenediamine; potassium carbonate in N,N-dimethyl acetamide; butan-1-ol T=110°C; Suzuki Coupling; 24 h; Inert atmosphere;
参考文献
Wang, Kun; Fu, Qi; Zhou, Rong; Zheng, Xueli; Fu, Haiyan; Chen, Hua; Li, Ruixiang
Applied Organometallic Chemistry, 2013 , vol. 27, # 4 p. 232 - 238
1003-09-4
2-溴噻吩
+
106032-16-0
→
反应条件
2404-89-9
2,3-联噻吩
反应条件
[1,3-bis(diphenylphosphino) propane] dichloronickel(II) in diethyl ether Heating;
参考文献
Jayasuriya, Nimal; Kagan, Jacques
Heterocycles, 1986 , vol. 24, # 8 p. 2261 - 2264
1003-09-4
2-溴噻吩
+
70161-87-4
→
反应条件
2404-89-9
2,3-联噻吩
反应条件
bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide Condensation; 20 h; Heating;
参考文献
Al-Taweel, Samir A.; Al-Saraierh, Hassan F.
Phosphorus, Sulfur and Silicon and Related Elements, 1999 , vol. 155, p. 47 - 57
1003-09-4
2-溴噻吩
+
872-31-1
→
反应条件
2404-89-9
2,3-联噻吩
反应条件
[1,3-bis(diphenylphosphino) propane] dichloronickel(II); magnesium 1.) Et2O, 2.) heating, 24 h;
参考文献
Montheard, Jean-Pierre; Delzant, Jean-Francois; Gazard, Maryse
Synthetic Communications, 1984 , vol. 14, # 3 p. 289 - 292
1003-09-4
2-溴噻吩
→
反应条件
188290-36-0
+
2404-89-9
2,3-联噻吩
+
34557-54-5
+
492-97-7
反应条件
PyrolysisIR laser powering; Product distribution; Further Variations:Reagents;
参考文献
Hore, Nathan R.; Russell, Douglas K.
New Journal of Chemistry, 2004 , vol. 28, # 5 p. 606 - 613
1003-09-4
2-溴噻吩
+
1066-54-2
→
反应条件
23975-15-7
反应条件
water; 1,8-diazabicyclo[5.4.0]undec-7-ene; triphenylphosphine; Pd-Ni in toluene T=80°C; Sonogashira coupling; 18 h;
参考文献
Son, Seung Uk; Jang, Youngjin; Park, Jongnam; Na, Hyon Bin; Park, Hyun Min; Yun, Hyung Joong; Lee, Jouhahn; Hyeon, Taeghwan
Journal of the American Chemical Society, 2004 , vol. 126, # 16 p. 5026 - 5027
1003-09-4
2-溴噻吩
+
471-25-0
→
反应条件
23975-15-7
反应条件
bis-triphenylphosphine-palladium(II) chloride; octadecyl-trimethylammonium chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,4-di(diphenylphosphino)-butane in water 12 h; Heating;
参考文献
Park, Kyungho; Bae, Goun; Park, Ahbyeol; Kim, Yong; Choe, Jaehoon; Song, Kwang Ho; Lee, Sunwoo
Tetrahedron Letters, 2011 , vol. 52, # 5 p. 576 - 580
1003-09-4
2-溴噻吩
→
反应条件
23975-15-7
反应条件
dichloro bis(acetonitrile) palladium(II) in N,N-dimethyl-formamide T=25°C; heteroarylation; 16 h;
参考文献
Ng; Novak; Wang; Huang
Tetrahedron, 1997 , vol. 53, # 39 p. 13339 - 13350
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