in neat (no solvent) BaO reacts with CHI3 under formation of BaI2 after some days; CHI3 decomposites under formation of I2 and HI at influence of light;;
参考文献
Bulletin de la Societe Chimique de France, , vol. 3, p. 704 - 705
in further solvent(s) N2 atmosphere; refluxing of KI and H3PO4; sepn. in trap (263 K), freezing in trap (77 K), drying (over P2O5), removalof I2 by treatment with red phosphorus, further purifn. by freeze-thaw cycles between 193 and 77 K;
参考文献
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, , vol. 82, p. 737 - 744
in neat (no solvent) byproducts: caesium borates, H2O; cesium iodide and boric acid were heated together to temp. in the range 400-1000 °C;; nitrogen-matrix IR of the obtained vapor products;;
参考文献
High temperature science, , vol. 24, # 3 p. 125 - 171
in further solvent(s) byproducts: Et2SO2, CH2CHS(O)CH2CH3; I2 added to Et2SO-H2O; monitored by UV-vis spectra, conductometric and pH-metric study, argentometric titration and gas chromy.;
参考文献
Russian Journal of General Chemistry, , vol. 76, # 11 p. 1801 - 1803
