in neat (no solvent) byproducts: CF3SiBr; under dry N2, in a sealed tube, 60 h at room temp., molar ratio of silane and HBr was 1:1, an other non-volatile product was also formed; fractionated distn. at a low-temp. column, S-compds. were trapped at 143K, SiF4 at 77 K;
参考文献
Beckers, Helmut; Buerger, Hans
Zeitschrift fur Anorganische und Allgemeine Chemie, 2001 , vol. 627, # 6 p. 1217 - 1224
Lespieau
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1904 , vol. 138, p. 1051
Bulletin de la Societe Chimique de France, 1905 , vol. <3>33, p. 466
in hydrogen bromide aq. HBr; formation on neutralization of cis-(Pt(NH3)2(OH)2)-soln. with HBr-soln.;;
参考文献
Drew, H. D. K.; Pinkard, F. W.; Wardlaw, W.; Cox, E. G.
Journal of the Chemical Society, 1932 , p. 988 - 1004
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Gmelin Handbook: Pt: MVol.D, 107, page 248 - 250
in n-heptane cooling VCl4 in heptane (100ml) at ca -35°C; connecting to a vac. line and to a cylinder of HBr; introduction of HBr (color change from orange-brown to bright violet); repeating several times vac./HBr procedure, 5h; room temp., stirring, 15h;; filtration of formed ppt.; washing with heptane; drying in vac.; elem. anal.;;
参考文献
Calderazzo, Fausto; Maichle-Moessmer, Caecilie; Pampaloni, Guido; Straehle, Joachim
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1993 , # 5 p. 655 - 658
