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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
100465-51-8
合成路线
(共 6 条)
100465-51-8
→
反应条件
18531-94-7
R-1,1'-联-2-萘酚
反应条件
1: water / cholesterol esterase, sodium taurocholate / diethyl ether / 65 h / pH = 7.2 2: CH3ONa / methanol / 2 h / Ambient temperature View Scheme
参考文献
Kazlauskas, Romas J.
Journal of the American Chemical Society, 1989 , vol. 111, # 13 p. 4953 - 4959
100465-51-8
→
反应条件
18531-94-7
R-1,1'-联-2-萘酚
+
18531-99-2
S-联萘酚
反应条件
water; cholesterol esterase in diethyl ether T=25°C; catalyst activated by sodium taurocholate; pH = 7.00; rate of hydrolysis (relative to cholesterol acetate); Product distribution;
参考文献
Fujimoto, Yoshinori; Iwadate, Hiroshi; Ikekawa, Nobuo
Journal of the Chemical Society, Chemical Communications, 1985 , # 19 p. 1333 - 1334
100465-51-8
→
反应条件
18531-94-7
R-1,1'-联-2-萘酚
+
18531-99-2
S-联萘酚
+
100465-51-8
反应条件
in ethanol; hexane porcine pancreatic lipase, pH=7.4; Title compound not separated from byproducts;
参考文献
Miyano, Sotaro; Kawahara, Kan; Hashimoto Harukichi
Chemistry Letters, 1987 , p. 355 - 356
100465-51-8
→
反应条件
18531-94-7
R-1,1'-联-2-萘酚
+
18531-99-2
S-联萘酚
反应条件
water; cholesterol esterase in diethyl ether T=25°C; catalyst activated by sodium taurocholate; pH = 7.00; rate of hydrolysis (relative to cholesterol acetate); Product distribution;
参考文献
Fujimoto, Yoshinori; Iwadate, Hiroshi; Ikekawa, Nobuo
Journal of the Chemical Society, Chemical Communications, 1985 , # 19 p. 1333 - 1334
100465-51-8
→
反应条件
18531-99-2
S-联萘酚
反应条件
water; cholesterol esterase; sodium taurocholic acid in diethyl ether 65 h; pH = 7.2; Yield given. Yields of byproduct given;
参考文献
Kazlauskas, Romas J.
Journal of the American Chemical Society, 1989 , vol. 111, # 13 p. 4953 - 4959
100465-51-8
→
反应条件
18531-94-7
R-1,1'-联-2-萘酚
+
18531-99-2
S-联萘酚
+
100465-51-8
反应条件
in ethanol; hexane porcine pancreatic lipase, pH=7.4; Title compound not separated from byproducts;
参考文献
Miyano, Sotaro; Kawahara, Kan; Hashimoto Harukichi
Chemistry Letters, 1987 , p. 355 - 356