acetic acid in acetic acid byproducts: HCl; heating under reflux; filtered, washed several times with dry acetic acid, dried under reduced pressure at 70°C;
参考文献
Misra, S. N.; Misra, T. N.; Mehrotra, R. C.
Journal of Inorganic and Nuclear Chemistry, 1963 , vol. 25, p. 201 - 203
Dhakarey, R.; Saxena, G. C.
Egypt. J. Chem., 1983 , vol. 26, p. 125 - 132
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Gmelin Handbook: Sc: MVol.D4, 1.4.10, page 52 - 53
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反应条件
in neat (no solvent) byproducts: LiCl, LaH2; (LiBH4+1/3LaCl3) mixt. (ball milled for 1-48 h) evacuated to 1E-3 Torr, heated at rate 2°C/min from room temp. to 450-600°C; DSC-TG-MS, XRD;
参考文献
Journal of Alloys and Compounds, , vol. 509, # 3 p. 751 - 757
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反应条件
in gas graphite disk impregnated with La by exposire to a boiling satd. aq. soln. of LaCl3 followed by rinsing and drying was vaporized by pulse laserat 532 nm using He carrier (ca. 1 atm); reaction products were analyzed by a time-of-flight mass spectrometer;
参考文献
Journal of the American Chemical Society, , vol. 107, p. 7779 - 7780
→
反应条件
in gas graphite disk impregnated with La by exposire to a boiling satd. aq. soln. of LaCl3 followed by rinsing and drying was vaporized by pulse laserat 532 nm using He carrier (ca. 1 atm); reaction products were analyzed by a time-of-flight mass spectrometer;
参考文献
Health, J. R.; O'Brien, S. C.; Zhang, Q.; Liu, Y.; Curl, R. F.; et al.
Journal of the American Chemical Society, 1985 , vol. 107, p. 7779 - 7780
