1,1’-亚甲基双(4-氯苯)合成路线 （共 54 条）
反应条件
benzoyl chloride; pentacarbonyliron(0) in 1,3,5-trimethyl-benzene
Heating;
参考文献
Luh, Tien-Yau
Synthetic Communications, 1981 , vol. 11, # 10 p. 829 - 834
参考文献
Grummitt; Jenkins
Journal of the American Chemical Society, 1946 , vol. 68, p. 914
参考文献
Das, Suven; Froehlich, Roland; Pramanik, Animesh
Journal of Chemical Research, 2006 , # 2 p. 84 - 86
反应条件
sodium methylate
T=17°C; 3 h; Pt-anode, applied potl. vs. SCE 0.9-1.0 V, 3.7 F/mol, constant current 0.5 A, divided cell;
参考文献
Chiba, Toshiro; Okimoto, Mitsuhiro; Nagai, Hiroshi; Takata, Yoshiyuki
Journal of Organic Chemistry, 1983 , vol. 48, # 18 p. 2968 - 2972
反应条件
aluminium trichloride
T=-5 - -2°C; 0.45 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Halpern, Marc; Lysenko, Zenon
Journal of Organic Chemistry, 1989 , vol. 54, # 5 p. 1201 - 1203
反应条件
catalyst: K-L zeolite in chloroform
Kinetics; byproducts: 2-chlorodiphenylmethane, 4-chlorodiphenylmethane, HCl; at 333 K for 1 h; catalyst K-L zeolite; yields: 2-chlorodiphenylmethane 15.7 wt.percent, 4-chlorodiphenylmethane 3.9 wt.percent; not isolated; detd. by gas-chromy.;
参考文献
Kale; Singh
Journal of Molecular Catalysis A: Chemical, 2002 , vol. 184, # 1-2 p. 399 - 411
反应条件
ethanol; sodium ethanolate
T=145°C; anschliessendes Versetzen mit Wasser;
参考文献
Gaetzi; Stammbach
Helvetica Chimica Acta, 1946 , vol. 29, p. 563,570
反应条件
1: 85 percent / triethylamine / ethane-1,2-diol / 0.25 h / Heating
2: 85 percent / 1 h / 20 °C
View Scheme
参考文献
Das, Suven; Froehlich, Roland; Pramanik, Animesh
Journal of Chemical Research, 2006 , # 2 p. 84 - 86
反应条件
potassium hydroxide; ethylene glycol
参考文献
Smith et al.
Journal of Pharmacology and Experimental Therapeutics, 1946 , vol. 88, p. 359,364
Full Text Show Details
White; Sweeney
Public Health Rep., 1945 , vol. 60, p. 66,70
反应条件
potassium hydroxide; ethylene glycol
参考文献
Smith et al.
Journal of Pharmacology and Experimental Therapeutics, 1946 , vol. 88, p. 359,364
Full Text Show Details
White; Sweeney
Public Health Rep., 1945 , vol. 60, p. 66,70
