in neat (no solvent)
react. of a mixture of NO and gaseous HCl at 30-50 with or without catalyst; formation of NOCl and other products;;
参考文献
Noyes, W. A.
Journal of the American Chemical Society, 1925 , vol. 47, p. 2159 - 2164
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Gmelin Handbook: P: MVol.C, 192, page 441 - 443
in dichloromethane
mixt. of WCl6 and CH2Cl2 under N2 was stirred at room temp., N2 was replaced by NO for 30 min, NO was flushed out of system, mixt. was refluxedunder N2 for 3.5 h to removed ClNO; filtered, washed with CH2Cl2, dried under vac. at ambient temp.; elem. anal.;
参考文献
Hunter, Allen D.; Legzdins, Peter
Inorganic Chemistry, 1984 , vol. 23, p. 4198 - 4204
in dichloromethane
mixt. of WCl6 and CH2Cl2 under N2 was stirred at room temp., N2 was replaced by NO for 17 min, NO was flushed out of system, mixt. was refluxedunder N2 for 3.5 h to removed ClNO; filtered, washed with CH2Cl2, dried under vac. at ambient temp.; elem. anal.;
参考文献
Hunter, Allen D.; Legzdins, Peter
Inorganic Chemistry, 1984 , vol. 23, p. 4198 - 4204
Noyes, W. A.
Journal of the American Chemical Society, 1928 , vol. 50, p. 2902
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Gmelin Handbook: N: MVol.3, 2.5.3, page 725 - 729
in dichloromethane
NO was bubbled through the soln. of MoCl5 and CH3CN at room temp. for 1h, Ar atm.; concn., pptn. with pentane, filtration, washing with pentane, drying invac.; elem. anal.;
