Wingen, Lisa M.; Barney, William S.; Lakin, Matthew J.; Brauers, Theo; Finlayson-Pitts, Barbara J.
Journal of Physical Chemistry A, 2000 , vol. 104, # 2 p. 329 - 335
in neat (no solvent)
slowly passing NO2 into PCl3 (cooled with ice and NaCl) with evolution of NOCl (NO2 can be dried with CaCl2 or P2O5);; fractionation between 105 and 110°C yields PCl3 and P2O3Cl4 between 200 and 230°C, repeated distillation yields pure P2O3Cl4 at 210 to 215°C, fractionation can also be performed in vacuum or high vacuum;;
in gas
Kinetics; byproducts: O2NCF2C(O)F, O2NCF2CFClNO2; 322.8, 333.2 and 342.2 K, 13.0-90.2 Torr CF2CFCl and 9.3-89.5 Torr NO2 pressure, in the presence/absence of CF4 (277.6-458.5 Torr);
参考文献
Romano, Rosana M.; Della Vedova, Carlos O.; Czarnowski, Joanna
Zeitschrift fur Physikalische Chemie, 2002 , vol. 216, # 10 p. 1203 - 1217
Robbins, R. C.; Cadle, R. D.; Eckhardt, D. L.
J. Meteorol., 1959 , vol. 16, p. 53 - 56
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Gmelin Handbook: Cl: SVol.B2, 84, page 500 - 502
Thomas; Thomas
Transactions of the Faraday Society, 1961 , vol. 57, p. 266
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Gmelin Handbook: Cl: SVol.B2, 84, page 500 - 502
