water in tetrahydrofuran byproducts: H2; hydrolysis at 20°C; products not isolated;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 37, p. 583 - 588
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , vol. 37, p. 685 - 689
Mn(CO)3(4,4'-dimethyl-2,2'-bipyridine)(P(OPh)3) in tetrahydrofuran Irradiation (UV/VIS); at 298 K; excess of P-compound, irradiated at 546 nm; not isolated; IR;
chloroform in chloroform Irradiation (UV/VIS); soln. of educt in CHCl3 irradiated with SP 2025 argon-ion laser at 514.5 nm; not isolated; detected by IR;
参考文献
van der Graaf, T.; van Rooy, A.; Stufkens, D. J.; Oskam, A.
Inorganica Chimica Acta, 1991 , vol. 187, p. 133 - 140
in tetrahydrofuran byproducts: CH3CN; 5-mL aliquot of 1E-2 M Mn(CO)4P(OPh)3(1-) in THF added under Ar to 5 mL of 1E-2 M Mn(CO)5(MeCN)(1+) in THF at 22°C, react. complete within 5 min; not isolated; detected by IR;
in tetrahydrofuran byproducts: CH3CN; 5-mL aliquot of 1E-2 M NaMn(CO)4P(OPh)3 in THF added under Ar to 5 mL of 1E-2 M Mn(CO)5(MeCN)PF6 in THF at 22°C, react. complete within 5 min; not isolated; detected by IR;
