1,1'-bis-(diphenylphosphino)ferrocene; 1,3,5,7-tetra-azatricyclo[5.1.1.13,5]decane; bis(dibenzylideneacetone)-palladium(0) in N,N-dimethyl acetamide T=80°C; Mizoroki-Heck reaction; 6 h; Inert atmosphere;

sodium hydroxide; 4-hydroxyacetophenone oxime-derived palladacycle in water T=120°C; Hiyama reaction; 0.333333 h; microwave irradiation;

tributyl-amine; dnpf; palladium diacetate; tri-n-butylamine hydrochloride in methanol T=20 - 80°C; Heck Reaction; 17 h; Inert atmosphereGloveboxSchlenk techniqueSealed tube; Reagent/catalyst; regioselective reaction;

1,4-diaza-bicyclo[2.2.2]octane; 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate in methanol T=20 - 80°C; Heck Reaction; 38 h; Inert atmosphereGloveboxSchlenk techniqueSealed tube; Reagent/catalystTime; regioselective reaction;

magnesium; dichloro(P,P,P',P'-tetramethylethane-1,2-diphosphane)nickel(II) 1.) THF, 2.) THF, reflux, 36 h; Yield given. Multistep reaction;

1: triethylamine / dichloromethane / 5 h / 0 - 25 °C / Inert atmosphere 2: 1,1'-bis-(diphenylphosphino)ferrocene; 1,3,5,7-tetra-azatricyclo[5.1.1.13,5]decane; bis(dibenzylideneacetone)-palladium(0) / N,N-dimethyl acetamide / 6 h / 80 °C / Inert atmosphere View Scheme