双(三苯基膦)氯化铂(II)合成路线 （共 132 条）
反应条件
1: CHCl3 / chloroform 2: H2; CO / dichloromethane 3: dichloromethane 4: dichloromethane View Scheme
参考文献
Organometallics, , vol. 10, p. 4036 - 4045
反应条件
1: H2; CO / dichloromethane 2: dichloromethane 3: dichloromethane View Scheme
参考文献
Organometallics, , vol. 10, p. 4036 - 4045
反应条件
1: dichloromethane 2: CHCl3 / chloroform 3: H2; CO / dichloromethane 4: dichloromethane 5: dichloromethane View Scheme
参考文献
Organometallics, , vol. 10, p. 4036 - 4045
反应条件
in chloroform Pt-complex and PPh3 were dissolved in CHCl3, kept under stirring for 20 h at room temp.; solvent was evapd. under reduced pressure, filtered, washed with Et2O, dried in stream of dry air; elem. anal.;
参考文献
Inorganic Chemistry, , vol. 41, # 3 p. 470 - 478
反应条件
HCl in dichloromethane N2-atmosphere; shaking of equimolar amts. of Pt-complex with 0.115 M HCl(3 days); filtration, addn. of Et2O to filtrate, concn.; evapn. of filtrate to dryness, addn. of Et2O, recrystn. (CHCl3/Et2O);
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 287 - 294
反应条件
1: NaNH2 / ammonia 2: chloroform-d1 View Scheme
参考文献
Organometallics, , vol. 10, p. 615 - 623
反应条件
in acetone byproducts: cyclopropane-d, cyclopropane-d2; inert atmosphere; sealed tube, 2.5 equiv. DCl; gas chromy. of org. products;
参考文献
Inorganica Chimica Acta, , vol. 280, # 1-2 p. 193 - 201
反应条件
in toluene byproducts: cyclopropane, propene; inert atmosphere; 2.5 equiv. HCl; gas chromy. of org. products;
参考文献
Inorganica Chimica Acta, , vol. 280, # 1-2 p. 193 - 201
反应条件
in tetrahydrofuran addn. of aziridine to a stirred suspn. of Cl(NH3CH2CH2Cl) at 0°C; addn. of solid Pt-complex; stirring for 30 min at 0°C; stirring for 3 h at room temp.; taking to dryness (vac.); addn. of CH2Cl2; filtration; dropwise addn. of n-hexane; pptn.; filtration; washing with n-hexane; drying (vac.); elem. anal.;
参考文献
Inorganic Chemistry, , vol. 29, p. 3265 - 3268
反应条件
in benzene under inert gas Pt(PPh3)3 dissoved in benzene, CClPh3 in benzene added,soln. stirred for 2 h at ambient temp.; ppt. filtered off, washed with a little cold benzene, dried in vac.;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , # 8 p. 1448 - 1456
