CF3CO2H or CH3SO3H or HClO4; [((C14H8NCH(C4H2N)CEt2(C4H2N)CHN)2)Co2] in benzonitrile
Kinetics; (N2), Schlenk techniques; mixing soln. of Co complex, CF3CO2H or MeSO3H or HClO4, Cp2Fe, freezing, pumping, warming, addn. of PhCN with O2, shaking; UV;
参考文献
Devoille, Aline M. J.; Love, Jason B.
Dalton Transactions, 2012 , vol. 41, # 1 p. 65 - 72
Co2(DPB) in benzonitrile
Kinetics; oxidn. of O2 by Fe complex in PhCN in presence of catalytic amt. of Co compd. and HClO4 at 298 K; monitored spectrophotometrically;
参考文献
Fukuzumi, Shunichi; Okamoto, Ken; Gros, Claude P.; Guilard, Roger
Journal of the American Chemical Society, 2004 , vol. 126, # 33 p. 10441 - 10449
in methanol; water
Kinetics; investigation of equilibrium- and rate constants of the electron transfer react. at 20°C (ionic strength 0.02mol/dm*3, supporting electrolyte NaNO3);; not isolated, monitoring of react. by following the absorbance of the ferrocenium-ion at 617nm;;
参考文献
Carbone, Antonio I.; Cavasino, F. Paolo; Sbriziolo, Carmelo; Pelizetti, Ezio
Journal of Physical Chemistry, 1985 , vol. 89, # 16 p. 3578 - 3582
Triton X-100 or cetyltrimethylammonium nitrate in methanol; water
Kinetics; investigation of equilibrium- and rate constants of the electron transfer react. in micellar solns. (Triton X-100 (C18H17Ph(OC2H4)9.5OH) or cetyltrimetylammonium nitrate) at 20°C (ionic strength 0.02mol/dm*3,supporting electrolyte NaNO3);; not isolated, monitoring of react. by following the absorbance of the ferrocenium-ion at 617nm;;
参考文献
Carbone, Antonio I.; Cavasino, F. Paolo; Sbriziolo, Carmelo; Pelizetti, Ezio
Journal of Physical Chemistry, 1985 , vol. 89, # 16 p. 3578 - 3582
