Co2(DPX) in benzonitrile
Kinetics; oxidn. of O2 by Fe complex in PhCN in presence of catalytic amt. of Co compd. and HClO4 at 298 K; monitored spectrophotometrically;
参考文献
Das, Dipanwita; Lee, Yong-Min; Ohkubo, Kei; Nam, Wonwoo; Karlin, Kenneth D.; Fukuzumi, Shunichi
Journal of the American Chemical Society, 2013 , vol. 135, # 7 p. 2825 - 2834
C8H17C6H5(OC2H4)9.5OH or Na-dodecyl sulfate in methanol; water
Kinetics; investigation of equilibrium- and rate constants of the electron transfer react. in micellar solns. (Triton X-100 (C18H17Ph(OC2H4)9.5OH) or Na-dodecyl sulfate) at 20°C (ionic strength 0.02mol/dm*3, supportingelectrolyte NaNO3);; not isolated, monitoring of react. by following the absorbance of the ferrocenium-ion at 617nm;;
参考文献
Carbone, Antonio I.; Cavasino, F. Paolo; Sbriziolo, Carmelo; Pelizetti, Ezio
Journal of Physical Chemistry, 1985 , vol. 89, # 16 p. 3578 - 3582
in methanol; water
Kinetics; investigation of equilibrium- and rate constants of the electron transfer react. at 20°C (ionic strength 0.02mol/dm*3, supporting electrolyte NaNO3);; not isolated, monitoring of react. by following the absorbance of the ferrocenium-ion at 617nm;;
参考文献
Pelizzetti, Ezio; Giordano, Roberto
Journal of Inorganic and Nuclear Chemistry, 1981 , vol. 43, p. 2463 - 2466
in water; acetonitrile
Kinetics; other Radiation; laser flash photolysis (0.6 μs laser pulse at 200 mJ) react. of Cr complex with ferrocene deriv. in deaerated acetonitrile-H2O (70percent-30percent) at 25.+-.1°C; monitored by UV;
参考文献
Lee, Shoayung; Bakac, Andreja; Espenson, James H.
Inorganic Chemistry, 1989 , vol. 28, p. 1367 - 1369
in water; nitrobenzene
Kinetics; nitrobenzene soln. of ferrocene and water stirred for 1 h; aq. soln. of hexacyanoferrates injected to water phase; monitored spectrophotometrically;
in dimethyl sulfoxide
Kinetics; mixing of ferrocene with iodonium salt (3-5 msec); UV spectroscopy;
参考文献
Court, T. L.; Werner, H.
Journal of Organometallic Chemistry, 1974 , vol. 65, p. 245 - 251
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Gmelin Handbook: Ni: Org.Verb.2, 1.5.1.4.1, page 135 - 135
