in acetonitrile
adding acetonitrile soln. of cobaltocene to stirred soln. of complex in acetonitrile; concg., extg. (ether), filtering, chromy. (neutral alumina, hexane/CH2Cl2);
参考文献
Aase, Torill; Tilset, Mats; Parker, Vernon D.
Organometallics, 1989 , vol. 8, p. 1558 - 1563
Roling, P. V.; Rausch, M. D.
Syn. Reactiv. Inorg. Metal-Org. Chem., 1978 , vol. 8, p. 83 - 90
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Roling, P. V.
Diss. Abstr. Intern. B, Diss. Univ. of Massachusetts 1971 1971 , vol. 31, p. 6520
dimethylsulfide in tetrahydrofuran
Ar atmosphere; addn. of org. compd. to suspn. of Fe-compd. in THF, addn. Me2S, stirring (1 h); removal of solvent, suspending in Et2O, chromy. (silica, hexane/Et2O 50:50);
in pentane
excess solid naphthalene added to stirred soln. of Fe-complex in pentane, stirred for 15 min, 2,3-Me2-2,3-C2B9H9 in pentane added and stirred for 8 h; solid eluted with pentane from alumina column, solvent removed under vac., (Fe(C5H5)2) removed by vac. sublimation at 35°C, residue dissolved in THF and cooled to -20°C; elem. anal.;
参考文献
Garcia, Maria P.; Green, Michael; Stone, F. Gordon A.; Somerville, Richard G.; Welch, Alan J.; et al.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 2342 - 2348
in toluene
Irradiation (UV/VIS); under N2, C2H2 bubbled through toluene soln. of Fe-complex under UV irradiation for 5 d; solvent evapd. under reduced pressure, dissolved in CH2Cl2-hexane, chromd., three bands successively eluted with hexane, acetone-CH2Cl2 and neat MeOH; elem. anal.;
参考文献
Dyke, Andrew F.; Knox, Selby, A. R.; Naish, Pamela J.; Taylor, Graham E.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1297 - 1308
in dichloromethane
(Ar); a soln. of ruthenium and iron complexes in CH2Cl2 was heated under reflux for 3 h; evapn.; column chromy. (SiO2, CH2Cl2 or CH2Cl2/ethyl acetate); recrystn.;
参考文献
Katayama, Taku; Onitsuka, Kiyotaka; Takahashi, Shigetoshi
Journal of Organometallic Chemistry, 2000 , vol. 610, # 1-2 p. 31 - 37
