carbon mass ratio MoO2:C = 5:1; mixt. heated at 300°C in a flow of N2 loaded with CCl4; absence of moisture and oxygen; further by-product: Mo oxide chloride; removal of MoCl5 and Mo oxide chloride by vac. distn.;
参考文献
Shchukarev, S. A.; Vasil'kova, L. V.; Sharupin, B. N.
Vestn. Leningr. Univ. Fiz. Khim., 1959 , # 10 p. 72 - 77
C.A., 1959 , p. 17741
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Gmelin Handbook: Mo: SVol.B1, 3.3.5.4, page 66 - 67
in neat (no solvent) introduction of Cl2-gas (8-9 Torr/20 min/1.8 l/h) through purified (90min/H2 stream/1000°C) Mo powder (860 - 1160°C);; extraction of MoCl5 (CCl4); extraction MoCl4 (diethylether or water); further extraction (ethanol or water);;
参考文献
Mezin, A.; Lepage, J.; Paulmier, D.
Bulletin de la Societe Chimique de France, 1985 , # 4 p. 660 - 663
in solid byproducts: H2O; thermal decomposition of mixt. of MoO3 with poly(vinylchloride) or cerechlor 70 with different mole ratios in air, the heating rate of 10 deg/min at 20-850°C;
参考文献
Journal of thermal analysis, , vol. 32, # 6 p. 1915 - 1922
C.A., Vysokotemperaturnaya Korroziya i Zashchita Sverkhtugoplavkikh Metallov (High-Temperature Corrosion and Protection of Refractory Metals), Moskva 1977, 224 pp , vol. 88, p. 179375
