2-(苯磺酰)-1,3-环己二烯合成路线 （共 12 条）
反应条件
sodium hypochlorite; (S,S)-(-)-[N,N(1)-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoat(2-)]manganese(III) chloride in dichloromethane T=4°C;
参考文献
Tetrahedron Letters, , vol. 38, # 32 p. 5615 - 5618
反应条件
sodium hypochlorite in methanol 0.5 h; Inert atmosphere; optical yield given as percent ee;
参考文献
Ebrahimian, G. Reza; Du Jourdin, Xavier Mollat; Fuchs, Philip L.
Organic Letters, 2012 , vol. 14, # 10 p. 2630 - 2633
反应条件
N-ethyl-N,N-diisopropylamine; tetrakis(triphenylphosphine) palladium(0) in acetonitrile
5 h;
参考文献
Meyers, David J.; Fuchs, Philip L.
Journal of Organic Chemistry, 2002 , vol. 67, # 1 p. 200 - 204
反应条件
1: benzenesulphinic acid sodium salt With polystyrene-supported-SeCl in N,N-dimethyl-formamide
T=20°C; 6 h; solid-phase reaction;
2: cyclohexa-1,3-diene With boron trifluoride diethyl etherate in dichloromethane
T=20°C; 40 h;
3: With dihydrogen peroxide in tetrahydrofuran
T=20°C; 2 h;
参考文献
Qian; Huang
Synlett, 2001 , # 12 p. 1913 - 1916
反应条件
1: 86 percent / N-bromosuccinimide / CH2Cl2 / 0 - 10 °C
2: aq. Oxone / tetrahydrofuran; H2O / 0 - 20 °C
3: base
View Scheme
参考文献
Meyers, David J.; Fuchs, Philip L.
Journal of Organic Chemistry, 2002 , vol. 67, # 1 p. 200 - 204
反应条件
1: 88 percent / montmorillonite KSF / toluene / 7.5 h / Heating
2: 86 percent / N-bromosuccinimide / CH2Cl2 / 0 - 10 °C
3: aq. Oxone / tetrahydrofuran; H2O / 0 - 20 °C
4: base
View Scheme
参考文献
Meyers, David J.; Fuchs, Philip L.
Journal of Organic Chemistry, 2002 , vol. 67, # 1 p. 200 - 204
反应条件
1: 88 percent / montmorillonite KSF / toluene / 7.5 h / Heating
2: 86 percent / N-bromosuccinimide / CH2Cl2 / 0 - 10 °C
3: aq. Oxone / tetrahydrofuran; H2O / 0 - 20 °C
4: base
View Scheme
参考文献
Meyers, David J.; Fuchs, Philip L.
Journal of Organic Chemistry, 2002 , vol. 67, # 1 p. 200 - 204
反应条件
1: aq. Oxone / tetrahydrofuran; H2O / 0 - 20 °C
2: base
View Scheme
参考文献
Meyers, David J.; Fuchs, Philip L.
Journal of Organic Chemistry, 2002 , vol. 67, # 1 p. 200 - 204
反应条件
1.1: BuLi / tetrahydrofuran; hexane / -75 °C
1.2: tetrahydrofuran; hexane / -75 °C
2.1: tetrahydrofuran; hexane / 16 h / 20 °C
3.1: 82 percent / Na2CO3 / toluene / 22 h / Heating
View Scheme
参考文献
Brandaenge, Svante; Leijonmarck, Hans
Chemical Communications, 2004 , # 3 p. 292 - 293
反应条件
boron trifluoride diethyl etherate; 3-chloro-benzenecarboperoxoic acid in dichloromethane
Ambient temperature1) 17.5 h, 2) 15 min; Yield given;
参考文献
Baeckvall, Jan-E.; Najera, Carmen; Yus, Miguel
Tetrahedron Letters, 1988 , vol. 29, # 12 p. 1445 - 1448
