hydrogen; (p-toluenesulfonate)2palladium*1,3-bis(diphenylphosphino)propane T=100°C; P=30002.4 Torr; 4 h; var. of catalyst, its conc., solvent, partial pressure, temp., time, further with var. amounts of p-TsOH*H2O or H2O; Product distributionMechanism;
in neat (no solvent) T=280°C; 15 h; hydrogen transfer reactions on electronegative-substituted olefines; other olefines: fumarodinitrile, maleic anhydride; Product distribution;