反应条件
1: 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane With potassium tert-butylate; 1,3-bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene; zinc(II) chloride in tert-butyl methyl ether 0.5 h; Inert atmosphereSchlenk techniqueGlovebox; 2: 2-bromo-1-phenyl-propane; 2-(phenyl)ethyl bromide in tert-butyl methyl ether T=20°C; 12 h; Inert atmosphereSchlenk techniqueGlovebox;
参考文献
Bose, Shubhankar Kumar; Fucke, Katharina; Liu, Lei; Steel, Patrick G.; Marder, Todd B.
Angewandte Chemie - International Edition, 2014 , vol. 53, # 7 p. 1799 - 1803
Angew. Chem., 2014 , vol. 126, # 7 p. 1829 - 1834