反应条件
oxalyl dichloride in tetrahydrofuran byproducts: naphthalene, COS, CO; under Ar or N2; injecting PhNCS into stirred THF soln. of Na2(W(CO)5) (-78°C), injecting oxalyl chloride into stirred soln., stirring (5 min), warming to room temp.; removing solvent (reduced pressure), extg. (n-pentane), filtering, evapg. solvent (reduced pressure), subliming naphthalene and W(CO)6 (0.02 Torr, 40°C, 1 h), extg. residue (n-pentane), filtering, removing solvent (reduced pressure);
参考文献
Lee, Gary R.; Cooper, N. John
Organometallics, 1989 , vol. 8, p. 1538 - 1544
