2-羟基-2-环己烯-1-酮合成路线 （共 68 条）
反应条件
1,4-diaza-bicyclo[2.2.2]octane; oxygen O2, singlet; rose bengal T=40°C; 13 h; Irradiation;
参考文献
Tetrahedron, , vol. 41, # 11 p. 2163 - 2168
反应条件
oxygen O2, singlet; methylene blue in methanol T=30°C; 10 h; Irradiationyield depends on the reaction conditions (temp., sensitizer, solvent); Product distribution;
参考文献
Tetrahedron, , vol. 41, # 11 p. 2163 - 2168
反应条件
1: With bromine 2: With triethylamine
参考文献
Tetrahedron Letters, , vol. 43, # 13 p. 2347 - 2349
反应条件
1: 1) diisopropylamine, n-BuLi / 1) THF, -10 deg C, 30 min; 2) THF, -50 deg C 2: alcali 3: 100 percent / O2, methylene blue / methanol / 3 h / 5 °C / Irradiation 4: NaBH4, NaHCO3 / H2O 5: TsOH / benzene / Heating View Scheme
参考文献
Utaka, Masanori; Kuriki, Hidesuke; Sakai, Takashi; Takeda, Akira
Chemistry Letters, 1983 , p. 911 - 912
反应条件
toluene-4-sulfonic acid in benzene 16 h; Heating;
参考文献
Garg, Neeraj; Larhed, Mats; Hallberg, Anders
Journal of Organic Chemistry, 1998 , vol. 63, # 12 p. 4158 - 4162
反应条件
sodium hydride in tetrahydrofuran T=0°C;
参考文献
Quayle, Peter; Rahman, Shopna; Ward, E. Lucy M.; Herbert, John
Tetrahedron Letters, 1994 , vol. 35, # 22 p. 3801 - 3804
反应条件
oxygen O2, singlet; methylene blue in acetonitrile T=0°C; 13 h; Irradiation;
参考文献
Tetrahedron, , vol. 41, # 11 p. 2163 - 2168
反应条件
nitric acid; Cu; vanadium(5+) T=73°C; oxidation in the presence or in the absence of metal ion catalysators; Product distribution;
参考文献
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , p. 1677 - 1682
反应条件
dimethyl sulfoxide; trifluoroacetic anhydride in dichloromethane
T=-60°C; 1.5 h;
参考文献
Amon, Catherine M.; Banwell, Martin G.; Gravatt, G.Lance
Journal of Organic Chemistry, 1987 , vol. 52, # 22 p. 4851 - 4855
反应条件
dimethyl sulfoxide; trifluoroacetic anhydride in dichloromethane
T=-60°C; 1.5 h;
参考文献
Amon, Catherine M.; Banwell, Martin G.; Gravatt, G.Lance
Journal of Organic Chemistry, 1987 , vol. 52, # 22 p. 4851 - 4855
