2-羟基-2-环己烯-1-酮合成路线 （共 68 条）
反应条件
potassium hydroxide; tetrazolium blue in ethanol; water
T=60°C; 0.25 h;
参考文献
Jasiczak, Jan
Tetrahedron Letters, 1987 , vol. 28, # 37 p. 4323 - 4326
反应条件
sulfuric acid
T=20°C; 21 h;
参考文献
Habermehl, Gerhard G.; Wippermann, Irene
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1991 , vol. 46, # 10 p. 1421 - 1424
反应条件
copper diacetate; iodine in acetic acid
15 h; Heating;
参考文献
Horiuchi, C. Akira; Kiyomiya, Hiroshi; Takahashi, Masaaki; Suzuki, Yasuto
Synthesis, 1989 , # 10 p. 785 - 786
反应条件
water
T=75°C; microwave irradiation;
参考文献
Utsukihara, Takamitsu; Nakamura, Hiroaki; Watanabe, Masashige; Akira Horiuchi
Tetrahedron Letters, 2006 , vol. 47, # 52 p. 9359 - 9364
反应条件
sodium hydroxide in tetrahydrofuran
2 h; Yield given;
参考文献
Utaka, Masanori; Matsushita, Seishiro; Takeda, Akira
Chemistry Letters, 1980 , p. 779 - 780
反应条件
oxygen O2, singlet; TPP 2. Florisil in tetrachloromethane
T=-20°C; 0.05 h; Irradiation; Product distribution;
参考文献
Adam, Waldemar; Wang, Xiaoheng
Tetrahedron Letters, 1990 , vol. 31, # 9 p. 1245 - 1248
反应条件
enzyme from Populus balsamifera
T=27°C; incubation;
参考文献
Mattes, Benjamin R.; Clausen, Thomas P.; Reichardt, Paul B.
Phytochemistry (Elsevier), 1987 , vol. 26, # 5 p. 1361 - 1366
反应条件
silica gel in dichloromethane
various reaction times; Product distribution;
参考文献
Habermehl, Gerhard G.; Wippermann, Irene
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1991 , vol. 46, # 10 p. 1421 - 1424
反应条件
1: 1) diisopropylamine, n-BuLi / 1) THF, -10 deg C, 30 min; 2) THF, -50 deg C
2: Al2O3 / diethyl ether / 6 h / Ambient temperature
3: 100 percent / O2, methylene blue / methanol / 3 h / 5 °C / Irradiation
4: NaBH4, NaHCO3 / H2O
5: TsOH / benzene / Heating
6: 90 percent / H2 / Lindlar catalyst
View Scheme
参考文献
Utaka, Masanori; Kuriki, Hidesuke; Sakai, Takashi; Takeda, Akira
Chemistry Letters, 1983 , p. 911 - 912
反应条件
1: 1) diisopropylamine, n-BuLi / 1) THF, -10 deg C, 30 min; 2) THF, -50 deg C
2: Al2O3 / diethyl ether / 6 h / Ambient temperature
3: 100 percent / O2, methylene blue / methanol / 3 h / 5 °C / Irradiation
4: NaBH4, NaHCO3 / H2O
5: TsOH / benzene / Heating
View Scheme
参考文献
Utaka, Masanori; Kuriki, Hidesuke; Sakai, Takashi; Takeda, Akira
Chemistry Letters, 1983 , p. 911 - 912
