1-氨基-1-环戊基甲醇合成路线 （共 13 条）
反应条件
sodium tetrahydroborate; sodium hydrogencarbonate in ethanol; water T=15°C; Heating / reflux;
参考文献
Bayer Corporation
Patent: US6353006 B1, 2002 ;
Location in patent: Page column 30-31 ;
US 6353006 B1
反应条件
sodium tetrahydroborate; sulfuric acid in tetrahydrofuran; diethyl ether T=20°C; 15 h;
参考文献
Altenhoff, Gereon; Goddard, Richard; Lehmann, Christian W.; Glorius, Frank
Journal of the American Chemical Society, 2004 , vol. 126, # 46 p. 15195 - 15201
反应条件
lithium aluminium tetrahydride in diethyl ether Ambient temperature;
参考文献
Paulsen, Hans; Maass, Uwe
Chemische Berichte, 1981 , vol. 114, # 1 p. 346 - 358
反应条件
hydrogen; palladium on activated charcoal in ethyl acetate
参考文献
Tetrahedron, , vol. 57, # 50 p. 9899 - 9909
反应条件
1: 58 percent / HN3; Et3N / benzene; toluene / -70 - 20 °C 2: H2 / Pd/C / ethyl acetate View Scheme
参考文献
Tetrahedron, , vol. 57, # 50 p. 9899 - 9909
反应条件
1: 65.7 percent / KOH / ethanol / Ambient temperature 2: 85.7 percent / SOCl2 / toluene / Heating 3: NaN3 / H2O; acetone / 0 °C 4: benzene / Heating 5: 77.8 percent / LiAlH4 / diethyl ether / Ambient temperature View Scheme
参考文献
Chemische Berichte, , vol. 114, # 1 p. 346 - 358
反应条件
1: 85.7 percent / SOCl2 / toluene / Heating 2: NaN3 / H2O; acetone / 0 °C 3: benzene / Heating 4: 77.8 percent / LiAlH4 / diethyl ether / Ambient temperature View Scheme
参考文献
Chemische Berichte, , vol. 114, # 1 p. 346 - 358
反应条件
1: NaN3 / H2O; acetone / 0 °C 2: benzene / Heating 3: 77.8 percent / LiAlH4 / diethyl ether / Ambient temperature View Scheme
参考文献
Chemische Berichte, , vol. 114, # 1 p. 346 - 358
反应条件
sodium sulfate; trifluoroacetic acid in dichloromethane
T=4 - 20°C; 72 h;
参考文献
Bayer Corporation
Patent: US6353006 B1, 2002 ;
Location in patent: Page column 34 ;
US 6353006 B1
反应条件
triethylamine
1.) 3 h, 0 deg C, ether, 2.) 20 h, r.t., ether; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Paulsen, Hans; Maass, Uwe
Chemische Berichte, 1981 , vol. 114, # 1 p. 346 - 358
