5-甲基-2-异丙基环己酮合成路线 (共 238 条)
反应条件
palladium T=180 - 200°C;
参考文献
Komatsu; Kurata
Memoirs of the College of Science, Kyoto Imperial University, vol. <A> 9, p. 26
Chem. Zentralbl., 1926 , vol. 97, # I p. 1403
反应条件
T=350°C; P=110326 Torr;
参考文献
Adkins; Richards; Davis
Journal of the American Chemical Society, 1941 , vol. 63, p. 1320,1322
参考文献
Memoirs of the College of Science, Kyoto Imperial University, , vol. <A> 8, p. 39
Memoirs of the College of Science, Kyoto Imperial University, vol. <A> 9, p. 24,25
Chem. Zentralbl., , vol. 97, # I p. 1403
反应条件
1: benzene; sodium amide
3: bei der Ozonspaltung in CCl4 und bei der Oxidation mit Permanganat in kalter wss. Loesung
View Scheme
参考文献
Rupe; Gubler
Helvetica Chimica Acta, 1926 , vol. 9, p. 587
反应条件
1: 3-chloropropyl phenyl ether With di(tert-butyl)-biphenyl; lithium in tetrahydrofuran
T=-78°C; Metallation; 0.5 h;
2: cyclohexanone T=20°C; Addition; 1.5 h;
3: (-)-Menthone T=-78°C; Addition; 0.0833333 h; Further stages.;
参考文献
Foubelo, Francisco; Saleh, Sadiq A.; Yus, Miguel
Journal of Organic Chemistry, 2000 , vol. 65, # 11 p. 3478 - 3483
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; bromomagnesium diisopropylamide; triethylamine in diethyl ether
T=25°C; 8 h; Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Krafft, M. E.; Holton, Robert A.
Tetrahedron Letters, 1983 , vol. 24, # 13 p. 1345 - 1348
反应条件
P2S3
T=140°C; thio-1-menthone;
参考文献
Paquer, D.; Morin, L.; Vazeux, M.; Andrieu, C. G.
Recueil: Journal of the Royal Netherlands Chemical Society, 1981 , vol. 100, # 2 p. 52 - 58
反应条件
bis(trimethylsilyl)-sulfide; trimethylsilyl trifluoromethanesulfonate in acetonitrile
12 h; Ambient temperature;
参考文献
Degl'Innocenti; Capperucci; Mordini; Reginato; Ricci; Cerreta
Tetrahedron Letters, 1993 , vol. 34, # 5 p. 873 - 876
反应条件
1: 87 percent / 36 h / 55 °C
2: 81 percent / O2, bisacenaphthalenethiophene (BANT) / CH2Cl2 / 0.67 h / -78 °C / Irradiation
View Scheme
参考文献
Schneider, David F; Viljoen, Murray S
Tetrahedron, 2002 , vol. 58, # 26 p. 5307 - 5315
反应条件
acid; mercury cathode
Electrolysis; partial inactivated dextrorotatory menthenesubstances;
参考文献
Komatsu; Kurata
Memoirs of the College of Science, Kyoto Imperial University, vol. <A> 9, p. 25
Chem. Zentralbl., 1926 , vol. 97, # I p. 1403