Cope et al.
Journal of the American Chemical Society, 1941 , vol. 63, p. 3455
Full Text Show Details
Cope
Journal of the American Chemical Society, 1937 , vol. 59, p. 2327,2329
Cope et al.
Journal of the American Chemical Society, 1941 , vol. 63, p. 3455
Full Text Show Details
Cope
Journal of the American Chemical Society, 1937 , vol. 59, p. 2327,2329
1: allyltributylstannane; (η3-allylPdCl)2 in tetrahydrofuran
T=-60 - -40°C; 1 h;
2: benzaldehyde; α-cyanoacetic acid methyl ester With triphenylphosphine in tetrahydrofuran
T=-40 - 20°C; Title compound not separated from byproducts;
参考文献
Kiji, Jitsuo; Okano, Tamon; Nomura, Takaaki; Saiki, Kayoko; Sai, Torei; Tsuji, Jiro
Bulletin of the Chemical Society of Japan, 2001 , vol. 74, # 10 p. 1939 - 1945
catalyst: Pd(OAc)2-triphenylphosphine in tetrahydrofuran
under Ar; THF, CH2CHCH2Cl, allylstannane, NCCH2CO2CH3 and PhCHO added tomixt. of Pd(OAc)2 and PPh3 (molar ratio 17:19:11:10:1:2); heated at ref lux for 20 h; treated with water; extd. with ether; distd. under reduced pressure; detd. by GC;
参考文献
Kiji, Jitsuo; Okano, Tamon; Nomura, Takaaki; Saiki, Kayoko; Sai, Torei; Tsuji, Jiro
Bulletin of the Chemical Society of Japan, 2001 , vol. 74, # 10 p. 1939 - 1945
