4 A molecular sieve; sodium ethanolate; (3-cumenyl-5-Me-pyrazolyl)3-borate-Zn-OH T=150°C; P=75006 Torr; 20 h; var. of catalyst, reagent, pressure, temp., time, without NaOEt; Product distribution;
hydrogen; Ru(acac)3; methyl iodide T=130°C; P=105008 Torr; 5 h; rection in an autoclave; various reaction temperatures and reaction times; reaction of ethyl formate and diethyl ether with CO+H2; Product distributionMechanism;
参考文献
Journal of Organometallic Chemistry, , vol. 289, p. 107 - 116