1-hexene; di-tert-butyl peroxide T=140°C; 2 h; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 33, # 10 p. 2109 - 2112
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 10 p. 2310 - 2314
4 A molecular sieve; sodium ethanolate; (3-cumenyl-5-Me-pyrazolyl)3-borate-Zn-OH T=150°C; P=75006 Torr; 20 h; var. of catalyst, reagent, pressure, temp., time, without NaOEt; Product distribution;
in tetrahydrofuran byproducts: NO3(1-); alkoxide soln. addn. to F2C(NO2)2 soln. (molar ratio F2C(NO2)2:nucleophile=1:2), reacting (-10°C for 10-15 min), stirring (0°C for 1 h, further at 20°C for 2 h); salts. ppt. sepn. (CH2Cl2 addn.) after 1 d; chem. and GLC anal.;
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 52, p. 131 - 136
Zhurnal Obshchei Khimii, , vol. 52, p. 143 - 149
hydrogen; Ru(acac)3; methyl iodide T=130°C; P=105008 Torr; 5 h; rection in an autoclave; various reaction temperatures and reaction times; reaction of ethyl formate and diethyl ether with CO+H2; Product distributionMechanism;
参考文献
Journal of Organometallic Chemistry, , vol. 289, p. 107 - 116
