1,2,3,4,5,6,7,8-八硫杂环辛烷合成路线 （共 272 条）
反应条件
in neat (no solvent) mortaring of Cu(3-x)As, S8 and Cu, flushing of quartz ampoules with Ar, filling with this mixt., sealing, heating up to 750°C with a rateof 10 K/min, quenching; further intermediates (As, Cu(2-x)S, β-As4 S4); identification by X-ray diffraction;
参考文献
Mueller; Blachnik
Thermochimica Acta, 2002 , vol. 387, # 2 p. 153 - 171
反应条件
byproducts: SF6, SF4, SSF2; sepd. S8 and F2 in a high vac. app., cooling the fluorine to -196°C, pressure 5 atm, heating the S8 to 200°C, addn. of fluorine until the product dosn't become hot; condensation, cooling to -78°C, evapn. of volatile compds. for 0.5 h, detected by IR;
参考文献
Haas, A.; Willner, H.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1980 , vol. 462, p. 57 - 60
反应条件
in tetrachloromethane byproducts: S8; reduction of S4N4 with aq. hydrazine and S8 in CCl4 as solvent (furtherinert solvents are possible); further products;; evapn. of solvent, isolation by chromy. (silica gel or polystyrene gel);
参考文献
Garcia-Fernandez, H.
Phosphorus and Sulfur and the Related Elements, 1986 , vol. 28, p. 3 - 20
参考文献
Schmidt, M.; Siebert, W.; Rittig, F.
Chemische Berichte, 1968 , vol. 101, p. 281 - 284
反应条件
in neat (no solvent) High Pressure; SF6 and sulfur sealed in gold tube, heated for 24 h at 538°C (2000 atm); detected by IR spectra;
参考文献
Hagen, Arnulf P.; Terrell, Donald L.
Inorganic Chemistry, 1981 , vol. 20, p. 1325 - 1326
反应条件
melting and ignition of S on contact with F2;;
参考文献
Ann. Chim. Phys., , vol. 24, # 6 p. 224 - 339
反应条件
in benzene Stibane compound and sulfur in benzene are stirred for 0.5 h under cooling in Ar atmosphere.; filtn., removal of solvent under vac.;
参考文献
Ates, M.; Breunig, H. J.; Guelec, S.
Phosphorus, Sulfur and Silicon and the Related Elements, 1989 , vol. 44, p. 129 - 134
反应条件
in melt byproducts: H2; 850°C, 7 d, sealed Ta-ampoules; treatment with H2O;
参考文献
Schleid, Thomas; Lissner, Falk
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1994 , vol. 49, # 3 p. 340 - 346
反应条件
in tetrahydrofuran adding ((tBuCp)2TiCl)2 in THF to freshly sublimated S8 under stirring at room temp. , react. time: 3d , argon atmosphere; equil.; flash chromatography, elem. anal.;
参考文献
Phosphorus and Sulfur and the Related Elements, , vol. 36, p. 11 - 14
反应条件
in methanol Kinetics;
参考文献
Gmelin Handbook: C: MVol.D1, 3.4, page 31 - 44
