1,2,3,4,5,6,7,8-八硫杂环辛烷合成路线 （共 272 条）
反应条件
in neat (no solvent) isocyanate condensation onto borole (N2, -196°C), slow warming to room temp., heating (120°C, 14 h); distn. (high vac.); elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 361, p. 289 - 298
反应条件
in carbon disulfide Ar; S-compds. soln. addn. dropwise to Se-compd. soln. at -78°C; elem. anal., (77)Se-NMR;
参考文献
Phosphorus, Sulfur and Silicon and Related Elements, , vol. 124, p. 457 - 460
反应条件
in neat (no solvent) byproducts: SF4, N2; heating;
参考文献
Inorganic Chemistry, , vol. 25, p. 4451 - 4452
反应条件
decomposition at 190°C in a vacuum;
参考文献
Journal of the American Chemical Society, , vol. 112, # 17 p. 6385 - 6386
参考文献
Angewandte Chemie, International Edition in English, , vol. 11, p. 302
Angewandte Chemie, , vol. 84, p. 344 - 345
反应条件
in benzene 20°C, 48 h, in sealed tube; further unidentified products;
参考文献
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 142 - 149
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 163 - 171
C. A., , vol. 88, p. 151687
反应条件
in neat (no solvent) heating;
参考文献
Zeitschrift fur Anorganische und Allgemeine Chemie, , vol. 625, # 3 p. 385 - 388
反应条件
in dichloromethane; acetonitrile byproducts: SO4(2-); High Pressure; mixing Cu compd., S compd. in CH2Cl2/MeCN (1:1), stirring at room temp. for 30 min, sealing in autoclave, heating at 90°C for 20 h, various temp. (60 or 90°C), various times (1 h or 3-20 h); slow cooling (2.5°C/h) to ambient temp., isolation of crystals after storage at 0°C for 2 weeks, washing with Et2O, air drying, elem. anal.;
参考文献
Dalton Transactions, , vol. 40, # 4 p. 847 - 852
反应条件
in gas High Pressure; PF3 and SF6 (molar ratio 1.1:1) condences into gold tube at -196°C, sealed, held at 500°C (300 atm) for 24 h; detected by IR spectra;
参考文献
Inorganic Chemistry, , vol. 20, p. 1325 - 1326
反应条件
in toluene N2 atmosphere; addn. of soln. of SnMe3NEt2 to soln. of (ClBS2)2BN (20°C, stirring), heating (80°C, 72 h); removal of volatiles (vac.), dissolving (toluene/pentane), pptn. on standing (-15°C, 2 days), sepn. of crystals, redn. of vol., crystn.; sepn. (mechanically), washing (pentane); elem. anal.;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1311 - 1320
