in neat (no solvent) reaction by introducing N2O4 in O3-containing O2;;
参考文献
Lemon, J. T.; Lowry, T. M.
Journal of the Chemical Society, 1936 , p. 1409 - 1412
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Gmelin Handbook: O: MVol.4, 79, page 1157 - 1160
in neat (no solvent) byproducts: NOCl, NO2Cl; Irradiation (UV/VIS); passing dry N2O4 over the surface of freshly distd. PCl3 cooled at -40 °C and under irradiation with UV light; absortion under formation of a dark red liq.; expelling NO, N2O3, NOCl, NO2Cl;; isolation of liquid products by fractionation; liquid phase containing POCl3, P2O3Cl4 and P4O4Cl10; yield of P2O3Cl4 25 percent, P4O4Cl10 3 percent;;