meta-chloroperoxybenzoic acid; tri-n-butyl-tin hydride in benzene T=90°C; 12 h; in the presence of α-bromotoluene (competitor), relative reactivity; Mechanism;
参考文献
Journal of the American Chemical Society, , vol. 102, # 2 p. 692 - 697
H-mordenite zeolite (Si/Al ratio of 41.6, Na level of 130 ppm) mixed with alumina, pore forming reagent and extruded to form 1/12-inch cylindrical pellets (80percent sieve/20percent binder), calcined, mixed with ammonium heptamolybdate/water; impregnated catalyst (2percent Mo) calcined at 500° C. (1-3 h); macropore volume (>50 nm) = 0.288 cc/g T=382.212 - 398.879°C; P=11103.3 Torr; Product distribution / selectivity;
H-mordenite zeolite (Si/Al ratio of 41.6, Na level of 130 ppm) mixed with alumina, pore forming reagent and extruded to form 1/12-inch cylindrical pellets (80percent sieve/20percent binder), calcined, mixed with ammonium heptamolybdate/water; impregnated catalyst (2percent Mo) calcined at 500° C. (1-3 h); macropore volume (>50 nm) = 0.288 cc/g T=343.323 - 412.768°C; P=11103.3 Torr; Product distribution / selectivity;
methyl iodide; NiCl2((PPh3)P)2 in tetrahydrofuran addn. of Ni-catalyst and alkyl halide to soln. of BrYbC6H4YbBr, agitation (25°C); GLC;
参考文献
Rybakova, L. F.; Syutkina, O. P.; Garbar, A. V.; Petrov, E. S.
Journal of General Chemistry USSR (English Translation), 1988 , vol. 58, p. 934 - 936
Zhurnal Obshchei Khimii, 1988 , vol. 58, p. 1053 - 1055
