byproducts: boron hydride; High Pressure; under N2; diborane and trihalogen-borane was added to p-xylene at -130°C, then in a closed autoclave the mixture was heated to 130°C; at -195.8°C H2 was removed, at room temp. the residue of trihalogen-borane and diborane were removed;
zinc(II) chloride
T=120°C; temperatures, ΔH(excit.), ΔS(excit); the energy of activation; the preexponential factor.; Rate constantProduct distributionKinetics;
参考文献
Magerramov, M. N.
Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, p. 305 - 307
Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 2 p. 352 - 355
