hydrogen; RhH(CO)(triphenylphosphine)3; (4R,5R)-DIOP T=95°C; P=40 Torr; 3 h; study of the regio- and enantioselectivity in the hydroformylation reaction of various mono and disubstituted ethenes catalyzed by rhodium in the presence of (R,R)-Diop chiral ligand; Product distribution;
参考文献
Journal of Organometallic Chemistry, , vol. 279, p. 193 - 202
[rhodium(I)(carbonyl)2(acetylacetonate)]; hydrogen; (R,S)-Binaphos in benzene T=60°C; P=76000 Torr; 40 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 119, # 19 p. 4413 - 4423