diclazuril in water-d2 12 M DCl in D2O added to 0.1M soln. in CD3OD in NMR tube, allowed to stand for 5 h; detn. NMR spect.;
参考文献
Organometallics, , vol. 8, p. 804 - 812
→
反应条件
in water; acetone dropwise addn. of an aq. soln. of NiCl2*6H2O to a stirred soln. of ((CH3)3Sn)2S in acetone at room temp.; refluxing for 5 h;; filtration;;
参考文献
Doklady Chemistry (English Translation), , vol. 286 - 291, p. 305 - 308
Doklady Akademii Nauk SSSR, , vol. 289, p. 644 - 646
in dichloromethane Kinetics; Reaction mixt. is stirred for 3.5 h.; Ppt.is seperated by filtration, washed with CH2Cl2 and hexane to remove tin compds.;
in chloroform-d1; dichloromethane-d2 equiv. amounts in CDCl3/CD2Cl2 = 1:1 at -80°C, the metathesis to allylSnCl3 was instantaneous and quant., presence of unreacted aldehyde; (1)H-NMR, (13)C-NMR, (119)Sn-NMR;
参考文献
Journal of the American Chemical Society, , vol. 110, p. 984
