in dichloromethane Under N2, to a soln. of PtCl(C3H5)(P(CH3)2(C6H5) is added a soln. of Sn(CH3)3(C6H5), mixt. is stirred in the dark for 2 h.; Evapn., recrystn. at low temp.;
in dichloromethane Under N2, to a soln. of PtCl(C3H5)diphenylmethylphoshpine is added a soln. of Sn(CH3)3(C6H5), mixt. is stirred in the dark.; Evapn., recrystn. at low temp.;
methanol in methanol Kinetics; byproducts: Me3SiCl, Me3SiOSiMe3; a mixt. of Me3SiSnMe3 and Me2SiCl2 in methanol was kept for 150 min, reaction was followed by (1)H NMR spectroscopy; 70percent of the substrate had been consumed, rate const. is given; not isolated, identified by (1)H NMR spectrum;
参考文献
Journal of Organometallic Chemistry, , vol. 287, p. 25 - 38
