in chloroform-d1 mixing solns. of the Pd complex in CDCl3 with N,N-dimethylbenzylamine-d7 in CD3COOD and hexamethyldisiloxane, direct filtration into a NMR tube, thermostating in the dark (55°C, 240 h), intermediate filtration from Pd metal traces; not isolated; monitoring by 1H-NMR; detn. of the equilibrium constant;

ortho-palladated N,N-dimethylbenzylamine complex R1=H in chloroform-d1 T=55°C; 240 h; reversible reaction; Equilibrium constant;

in chloroform-d1 mixing solns. of the Pd complex in CDCl3 with N,N-dimethylbenzylamine-d7 in CD3COOD and hexamethyldisiloxane, direct filtration into a NMR tube, thermostating in the dark (55°C, 216 h), intermediate filtration from Pd metal traces; not isolated; monitoring by 1H-NMR; detn. of the equilibrium constant;

ortho-palladated N,N-dialkylbenzylamine complex R1=H in chloroform-d1 T=55°C; 360 h; reversible reaction; Equilibrium constant;

in chloroform-d1 mixing solns. of the Pd complex in CDCl3 with N,N-dimethylbenzylamine-d7 in CD3COOD and hexamethyldisiloxane, direct filtration into a NMR tube, thermostating in the dark (55°C, 240 h), intermediate filtration from Pd metal traces; not isolated; monitoring by 1H-NMR; detn. of the equilibrium constant;

ortho-palladated N,N-dimethylbenzylamine complex R1=H in chloroform-d1 T=55°C; 240 h; reversible reaction; Equilibrium constant;