trimethylsilyl trifluoromethanesulfonate in dichloromethane
T=-78°C; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
1: cyclohexanone With toluene-4-sulfonic acid
Inert atmosphereReflux;
2: acrolein in diethyl ether
Michael condensation; Inert atmosphere;
3: With hydrogenchloride in water
参考文献
Boltukhina, Ekaterina V.; Sheshenev, Andrey E.; Lyapkalo, Ilya M.
Tetrahedron, 2011 , vol. 67, # 30 p. 5382 - 5388
Crabb, Trevor A.; Turner, Christopher H.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980 , p. 1778 - 1782