(i) NaNH2, liq. NH3, (ii) /BRN= 605264/, Et2O; Multistep reaction;
参考文献
Hewertson,W.; Watson,H.R.
Journal of the Chemical Society, 1962 , p. 1490 - 1494
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反应条件
in tetrahydrofuran byproducts: ethylene; THF was distilled onto Te powder under N2, frozen (-196°C), PhLi syriged in, mixt. was allowed to thaw, after Te dissolution mixt. was refrozen (-196°C), Cl(CH2)2Cl added; reaction affords only Ph2Te2 and C2H4 even at low temps.;
参考文献
Hope, Eric G.; Kemmitt, Tim; Levason, William
Organometallics, 1987 , vol. 6, p. 206 - 207
Meadow; Reid
Journal of the American Chemical Society, 1934 , vol. 56, p. 2177,2178
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Tucker; Reid
Journal of the American Chemical Society, 1933 , vol. 55, p. 780
in gaseous matrix Mg(3P) generated by dc discharge applied between the metal containing crucible and ground, carrying Mg in a He flow to the react. zone in a Broida oven; introducing vapor of chlorine containing reactant; detn. by fluorescence;
参考文献
Shafizadeh, Niloufar; Rostas, Joelle; Taieb, Guy; Bourguignon, Bernard; Prisant, Michael G.
Chemical Physics, 1990 , vol. 142, p. 111 - 122
