CaH2 in neat (no solvent) byproducts: H2; react. under N2, slow addn. of the alcohol via syringe to B(OH)3 (ratio 3:1) and CaH2, cooling in a water bath, slow heating to 80-90°C for 12 h after abating the H2 gas evolution; distn. of the volatile products under reduced pressure (distn. pot temp. <= 120°C);
参考文献
Cole, T. E.; Quintanilla, R.; Rodewald, S.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1990 , vol. 20, p. 55 - 64
