2-甲基-2,4-戊二醇合成路线 （共 135 条）
参考文献
Searles et al.
Journal of Organic Chemistry, 1959 , vol. 24, p. 1770,1773
反应条件
tri-isopropoxy-borane in toluene T=50°C; Esterification;
参考文献
Huskens, Jurriaan; Reetz, Manfred T.
European Journal of Organic Chemistry, 1999 , # 8 p. 1775 - 1786
参考文献
Ipatieff; Pines
Journal of the American Chemical Society, 1945 , vol. 67, p. 1200
参考文献
Ipatieff; Pines
Journal of the American Chemical Society, 1945 , vol. 67, p. 1200
参考文献
Universal Oil Prod. Co.
Patent: US2406632 , 1944 ;
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Universal Oil Prod. Co.
Patent: US2406630 , 1944 ;
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Universal Oil Pord. Co.
Patent: US2406631 , 1944 ;
反应条件
boric acid in dichloromethane Heating;
参考文献
Blais,J. et al.
Journal of Organometallic Chemistry, 1974 , vol. 78, p. 323 - 337
反应条件
T=120 - 140°C; Erhitzen mit 2 Mol Edukt 2;
参考文献
Tryon
Journal of the American Chemical Society, 1947 , vol. 69, p. 972
参考文献
Ipatieff; Pines
Journal of the American Chemical Society, 1945 , vol. 67, p. 1200
反应条件
1: vinyl-magnesium bromide With boric acid trimethyl ester in tetrahydrofuran T=-78°C; 1 h; 2: With hydrogenchloride in tetrahydrofuran; diethyl ether T=20°C; 0.166667 h; 3: 1,1,3-trimethyl-1,3-propanediol in tetrahydrofuran; diethyl ether T=20°C; 1 h;
参考文献
Lightfoot, Andrew P.; Twiddle, Steven J.R.; Whiting, Andrew
Organic and Biomolecular Chemistry, 2005 , vol. 3, # 17 p. 3167 - 3172
反应条件
hydrogenchloride in tetrahydrofuran; diethyl ether under Ar; soln. CH2CHMgBr in THF added dropwise over 1 h to stirred soln. of anhyd. B(OMe)3 in THF at -78°C; stirred for 1 h; warmed to room temp.; 20percent HCl added; 10 min; soln. of diol in Et2O added; stirred for 1 h; two phases sepd.; aq. phase extd. with Et2O; combined org. extracts washed with satd. aq. NaHCO3 and water; dried (MgSO4); solvent evapd.; purified by Kugelroehr distn.;
参考文献
Lightfoot, Andrew P.; Twiddle, Steven J.R.; Whiting, Andrew
Organic and Biomolecular Chemistry, 2005 , vol. 3, # 17 p. 3167 - 3172
