4,4-二甲基-2-环己基-1-酮合成路线 （共 63 条）
反应条件
1: 98 percent / LiAlH4 / diethyl ether / 0.25 h / Heating 2: 85 percent / pyridine / diethyl ether 3: CH2Cl2 / 25 °C 4: 1.) O3, 2.) Et2NH / 1.) CH2Cl2, -78 deg C, 2.) reflux, 3 d 5: 93 percent / formic acid / 0.08 h / Heating View Scheme
参考文献
Journal of Organic Chemistry, , vol. 47, # 7 p. 1258 - 1267
反应条件
1: 85 percent / pyridine / diethyl ether 2: CH2Cl2 / 25 °C 3: 1.) O3, 2.) Et2NH / 1.) CH2Cl2, -78 deg C, 2.) reflux, 3 d 4: 93 percent / formic acid / 0.08 h / Heating View Scheme
参考文献
Journal of Organic Chemistry, , vol. 47, # 7 p. 1258 - 1267
反应条件
1: CH2Cl2 / 25 °C 2: 1.) O3, 2.) Et2NH / 1.) CH2Cl2, -78 deg C, 2.) reflux, 3 d 3: 93 percent / formic acid / 0.08 h / Heating View Scheme
参考文献
Journal of Organic Chemistry, , vol. 47, # 7 p. 1258 - 1267
反应条件
1: 1.) O3, 2.) Et2NH / 1.) CH2Cl2, -78 deg C, 2.) reflux, 3 d 2: 93 percent / formic acid / 0.08 h / Heating View Scheme
参考文献
Journal of Organic Chemistry, , vol. 47, # 7 p. 1258 - 1267
反应条件
boron trifluoride diethyl etherate; sodium iodide in acetonitrile T=25°C; 0.5 h;
参考文献
Mandal, Arun K.; Mahajan, S. W.
Tetrahedron, 1988 , vol. 44, # 8 p. 2293 - 2300
反应条件
1: 2,6-dimethylpyridine / tetrahydrofuran / 1 h / 0 °C 2: Eosin; potassium acetate; oxygen / ethanol / 4 °C / |Irradiation View Scheme
参考文献
Chemical Communications, , vol. 49, # 99 p. 11662 - 11664
反应条件
in isopropyl alcohol Irradiationfurther solvents; effect of the solvent on the product/yield distribution; Quantum yieldMechanismProduct distribution;
参考文献
Helvetica Chimica Acta, , vol. 66, # 8 p. 2534 - 2539
参考文献
Canadian Journal of Chemistry, , vol. 65, p. 1262 - 1278
反应条件
diiron nonacarbonyl; ammonium cerium(IV) nitrate; water 1) benzene, THF, 18 h, 45 deg C, 2) acetone, H2O, 12 h, r.t.; Yield given. Multistep reaction;
参考文献
Chemische Berichte, , vol. 116, # 1 p. 243 - 253
反应条件
p-mentha-1,8-diene; palladium on activated charcoal 0.5 h; Heating;
参考文献
Holleben, Maria Luiza A. von; Zucolotto, Monica; Zini, Claudia A.; Oliveira, Eduardo R.
Tetrahedron, 1994 , vol. 50, # 4 p. 973 - 978
