T=30 - 40°C; 6 h; various time; KineticsMechanismProduct distribution;
参考文献
Nurtdinov, S. Kh.; Kashirskaya, I. M.; Ismagilova, N. M.; Gubaidullina, R. Sh.; Zykova, T. V.; et al.
J. Gen. Chem. USSR (Engl. Transl.), 1980 , vol. 50, # 6 p. 1297 - 1301,1049 - 1052
1: chloro-diphenylphosphine With sodium in tetrahydrofuran T=35°C; 2.5 h; 2: lithium 2-chlorobenzoate in tetrahydrofuran T=0°C; 3 h; 3: With hydrogenchloride in tetrahydrofuran; water
1: chloro-diphenylphosphine With potassium in 2-methyl tetrahydrofuran T=81 - 83°C; 2 h; Industry scale; 2: o-chlorobenzoic acid potassium salt in tetrahydrofuran; 2-methyl tetrahydrofuran T=25°C; 10 h; Industry scale; 3: in tetrahydrofuran; 2-methyl tetrahydrofuran Acidic conditionsIndustry scale; Product distribution / selectivity;
1: chloro-diphenylphosphine With sodium in tetrahydrofuran T=65 - 66°C; 2 h; Industry scale; 2: o-chloro-sodium benzoate in tetrahydrofuran T=25°C; 10 h; Industry scale; 3: in tetrahydrofuran Acidic conditionsIndustry scale; Product distribution / selectivity;
