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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
醋酸乙烯酯
合成路线
(共 1274 条)
108-05-4
醋酸乙烯酯
+
3391-10-4
1-(4-氯苯基)乙醇
→
反应条件
3391-10-4
1-(4-氯苯基)乙醇
+
19759-43-4
反应条件
steapsin lipase in hexane T=55°C; 48 h; Enzymatic reaction; optical yield given as percent ee;
参考文献
Dhake, Kishor P.; Deshmukh, Krishna M.; Wagh, Yogesh S.; Singhal, Rekha S.; Bhanage, Bhalchandra M.
Journal of Molecular Catalysis B: Enzymatic, 2012 , vol. 77, p. 15 - 23
108-05-4
醋酸乙烯酯
+
7287-82-3
1-(2-甲基苯基)乙醇
→
反应条件
7287-82-3
1-(2-甲基苯基)乙醇
+
42070-90-6
+
205237-75-8
反应条件
Escherichia coli BioH in hexane T=35°C; 28 h; Resolution of racemate; optical yield given as percent eeenantioselective reaction;
参考文献
Wang, Bo; Tang, Xiaoling; Liu, Ji; Yu, Hongwei
Tetrahedron Letters, 2010 , vol. 51, # 48 p. 6360 - 6364
108-05-4
醋酸乙烯酯
+
106-22-9
→
反应条件
7540-51-4
+
1117-61-9
+
20425-54-1
反应条件
porcine pancreatic lipase in hexane 24 h; Title compound not separated from byproducts;
参考文献
Tetrahedron Asymmetry, , vol. 13, # 13 p. 1373 - 1378
108-05-4
醋酸乙烯酯
+
4187-87-5
→
反应条件
4187-87-5
+
84681-19-6
+
116119-86-9
反应条件
ChiroCLEC-PC; water in toluene Acetylation; enzymatic resolution; 6.5 h; Enzymatic reaction; Product distribution; Further Variations:reaction time;
参考文献
Chen, Peiran; Zhu, Xiyin
Journal of Molecular Catalysis B: Enzymatic, 2013 , vol. 97, p. 184 - 188
108-05-4
醋酸乙烯酯
+
4187-87-5
→
反应条件
4187-87-5
+
84681-19-6
反应条件
novozyme 435 in benzene T=32°C; 0.333333 h; Product distribution; Further Variations:Solventstime;
参考文献
Raminelli, Cristiano; Comasseto, Joao V.; Andrade, Leandro H.; Porto, Andre L.M.
Tetrahedron Asymmetry, 2004 , vol. 15, # 19 p. 3117 - 31722
108-05-4
醋酸乙烯酯
+
580-13-2
→
反应条件
612-78-2
+
93-08-3
反应条件
tri-n-butyltin methoxide; bis (triortho-tolylphosphine)palladium(II) chloride in dimethyl sulfoxide T=100°C; 14 h;
参考文献
Jean, Mickael; Renaulty, Jacques; Uriac, Philippe; Capet, Marc; Van De Weghe, Pierre
Organic Letters, 2007 , vol. 9, # 18 p. 3623 - 3625
4754-27-2
+
108-05-4
醋酸乙烯酯
→
反应条件
5096-11-7
+
27854-86-0
反应条件
Lipase PS-C in di-isopropyl ether T=35°C; 6.5 h;
参考文献
Itoh, Toshiyuki; Matsushita, Yuichi; Abe, Yoshikazu; Han, Shi-Hui; Wada, Shohei; Hayase, Shuichi; Kawatsura, Motoi; Takai, Shigeomi; Morimoto, Minoru; Hirose, Yoshihiko
Chemistry - A European Journal, 2006 , vol. 12, # 36 p. 9228 - 9237
75-15-0
+
108-05-4
醋酸乙烯酯
+
865-47-4
+
74-88-4
→
反应条件
540-88-5
+
78263-38-4
反应条件
1: vinyl acetate; potassium tert-butylate in tetrahydrofuran T=-78°C; Metallation; Substitution; 2: carbon disulfide in tetrahydrofuran T=0°C; Addition; 0.75 h; 3: methyl iodide in tetrahydrofuran T=0°C; Methylation; 12 h;
参考文献
Synlett, , # 9 p. 1345 - 1347
108-05-4
醋酸乙烯酯
+
29783-26-4
→
反应条件
60176-77-4
反应条件
Pancreatin; triethylamine in tetrahydrofuran T=20°C; 3 h;
参考文献
Synlett, , # 3 p. 485 - 487
108-05-4
醋酸乙烯酯
+
29783-26-4
→
反应条件
54664-61-8
+
60176-77-4
反应条件
triethylamine in tetrahydrofuran 4 h; Ambient temperaturelipase from Mucor sp.;
参考文献
Journal fuer Praktische Chemie (Leipzig), , vol. 333, # 3 p. 497 - 499
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