1: cyclohexanol With potassium hydroxide in tetrahydrofuran 1 h; RefluxCooling with iceInert atmosphere; 2: carbon disulfide in tetrahydrofuran T=20°C; Cooling with iceInert atmosphere;
参考文献
Dumur, Frederic; Mayer, Cedric R.
Helvetica Chimica Acta, 2013 , vol. 96, # 5 p. 889 - 896
CaH2 in neat (no solvent) byproducts: H2; react. under N2, slow addn. of the alcohol via syringe to B(OH)3 (ratio 3:1) and CaH2, cooling in a water bath, slow heating to 80-90°C for 12 h after abating the H2 gas evolution; distn. of the volatile products under reduced pressure (distn. pot temp. <= 120°C);
参考文献
Cole, T. E.; Quintanilla, R.; Rodewald, S.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1990 , vol. 20, p. 55 - 64
