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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
邻溴吡啶
合成路线
（共 1098 条）
109-04-6
邻溴吡啶
+
2005-43-8
2-溴喹啉
→
反应条件
7491-86-3
2-吡啶-2-基喹啉-4-羧酸
反应条件
1: 2-bromoquinoline With (nBu)3MgLi in tetrahydrofuran; diethyl ether; hexane T=-30 - -10°C; 2: 2-bromo-pyridine With 1,1'-bis-(diphenylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran; diethyl ether; hexane T=-10 - 20°C; 19 h;
参考文献
Dumouchel, Sylvain; Mongin, Florence; Trecourt, Francois; Queguiner, Guy
Tetrahedron, 2003 , vol. 59, # 43 p. 8629 - 8640
109-04-6
邻溴吡啶
→
反应条件
7491-86-3
2-吡啶-2-基喹啉-4-羧酸
反应条件
1.1: n-butyllithium / tetrahydrofuran / 1 h / -78 °C / |Inert atmosphere 1.2: 2 h / -78 °C / |Inert atmosphere 1.3: 5 h / 20 °C / |Inert atmosphere 2.1: methanol / 15 h / 20 °C / |Inert atmosphere 3.1: PdCl2dcpp; copper(l) iodide; 2-methylamino-ethanol / N,N-dimethyl-formamide / 16 h / 100 °C / |Inert atmosphere View Scheme
参考文献
Sakashita, Shohei; Takizawa, Miho; Sugai, Juugaku; Ito, Hajime; Yamamoto, Yasunori
Organic Letters, 2013 , vol. 15, # 17 p. 4308 - 4311
109-04-6
邻溴吡啶
+
5980-97-2
2,4,6-三甲基苯硼酸
→
反应条件
75722-64-4
反应条件
Suzuki-Miyaura cross coupling;
参考文献
Mita, Tsuyoshi; Michigami, Kenichi; Sato, Yoshihiro
Organic Letters, 2012 , vol. 14, # 13 p. 3462 - 3465
109-04-6
邻溴吡啶
+
123-30-8
对氨基苯酚
→
反应条件
76471-08-4
反应条件
hydrogenchloride in water; ethyl acetate; N,N-dimethyl-formamide; mineral oil; Petroleum ether
参考文献
Knoll Aktiengesellschaft
Patent: US5780482 A1, 1998 ;
109-04-6
邻溴吡啶
+
13922-41-3
1-萘硼酸
→
反应条件
76759-26-7
2-萘基吡啶
反应条件
potassium tert-butylate; ClPd[N,N(2,6-iPr2C6H3)2-imidazol-2-yl]cinnamyl in isopropyl alcohol T=20°C; Suzuki-Miyaura cross-coupling reaction; 3.5 h;
参考文献
Navarro, Oscar; Marion, Nicolas; Mei, Jianguo; Nolan, Steven P.
Chemistry - A European Journal, 2006 , vol. 12, # 19 p. 5142 - 5148
109-04-6
邻溴吡啶
+
91-20-3
萘
→
反应条件
76759-26-7
2-萘基吡啶
+
66318-88-5
反应条件
Cp2Ni; triethyl borane; potassium tert-butylate in tetrahydrofuran T=80°C; 12 h; Inert atmosphere;
参考文献
Kobayashi, Osamu; Uraguchi, Daisuke; Yamakawa, Tetsu
Organic Letters, 2009 , vol. 11, # 12 p. 2679 - 2682
109-04-6
邻溴吡啶
+
91-20-3
萘
→
反应条件
76759-26-7
2-萘基吡啶
反应条件
1: naphthalene With n-butyllithium in tetrahydrofuran T=-50°C; 2 h; 2: With zinc(II) chloride in tetrahydrofuran T=25°C; 1.5 h; 3: 2-bromo-pyridine With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=20°C; 2 h;
参考文献
Jiang, Jiaxing; Jiang, Changyun; Yang, Wei; Zhen, Hongyu; Huang, Fei; Cao, Yong
Macromolecules, 2005 , vol. 38, # 10 p. 4072 - 4080
109-04-6
邻溴吡啶
+
68716-52-9
1-萘硼酸频呐醇酯
→
反应条件
76759-26-7
2-萘基吡啶
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethylene glycol dimethyl ether; ethanol; water T=20°C; Suzuki coupling; RefluxInert atmosphere;
参考文献
Tian, Nan; Thiessen, Alexander; Schiewek, Ralf; Schmitz, Oliver J.; Hertel, Dirk; Meerholz, Klaus; Holder, Elisabeth
Journal of Organic Chemistry, 2009 , vol. 74, # 7 p. 2718 - 2725
109-04-6
邻溴吡啶
→
反应条件
76759-26-7
2-萘基吡啶
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in ethanol T=100°C; Suzuki Coupling; 18 h; Inert atmosphere;
参考文献
Goggins, Sean; Rosevere, Eleanor; Bellini, Clement; Allen, Joseph C.; Marsh, Barrie J.; Mahon, Mary F.; Frost, Christopher G.
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 1 p. 47 - 52
109-04-6
邻溴吡啶
+
201230-82-2
+
13922-41-3
1-萘硼酸
→
反应条件
76759-26-7
2-萘基吡啶
+
107341-55-9
反应条件
caesium carbonate; 1,3-bis(2,4,6-trimethylphenyl)imidazolinium chloride; palladium diacetate in 1,4-dioxane T=120°C; P=37503 Torr; 15 h;
参考文献
Maerten, Eddy; Sauthier, Mathieu; Mortreux, Andre; Castanet, Yves
Tetrahedron, 2007 , vol. 63, # 3 p. 682 - 689
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