hydrogen; rhenium in methanol T=100°C; P=18751.5 Torr; 4 h; various rhenium complexes with cyclic sulfides as catalysts of hydrogenation and isomeization of olefins; Product distribution;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 37, p. 641 - 644
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 4 p. 755 - 759
Cp'2Mo2Co2S3(CO)4 in decalin Ea, ΔH<*>, ΔS<*>; desulfurization of aromatic and aliphatic thiols mediated by Mo/Co/S cluster; reaction kinetics and mechanism; effect of thiol concentration; effect of CO on rate of desulfurization; desulfurization of thiolate anions; Thermodynamic data;
参考文献
Journal of the American Chemical Society, , vol. 119, # 5 p. 1027 - 1036
molybdenum carbides; hydrogen in gas T=359.9°C; P=757.6 Torr; Eact; var. Mo catalysts: carbides, nitrides and sulfides, var. temperature; Thermodynamic dataProduct distribution;
