1: n-butyllithium With sulfur in tetrahydrofuran; hexane
T=0°C;
2: With water in tetrahydrofuran; hexane
0.166667 h;
3: acrolein in tetrahydrofuran; hexane
Michael type reaction; 0.5 h; Further stages.;
参考文献
Comasseto, Joao V.; Gariani, Rogerio A.; Princival, Jefferson L.; Dos Santos, Alcindo A.; Zinn, Fabiano K.
Journal of Organometallic Chemistry, 2008 , vol. 693, # 17 p. 2929 - 2936
1: n-butyllithium With chiral amino silyl ether in pentane
T=20°C; 0.333333 h;
2: benzaldehyde in pentane
T=-116°C; 1 h; Further stages. Title compound not separated from byproducts.;
参考文献
Liu, Jia; Li, Deyu; Sun, Chengzao; Williard, Paul G.
Journal of Organic Chemistry, 2008 , vol. 73, # 11 p. 4045 - 4052
chiral diamine reagent in diethyl ether
T=-120°C; 3 h;
参考文献
Kanoh, Shygeyoshi; Muramoto, Hiroki; Maeda, Kazunobu; Kawaguchi, Naotaka; Motoi, Masatoshi; Suda, Hiroshi
Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 6 p. 2244 - 2246
