1: n-butyllithium With Methyltriphenylphosphonium bromide in tetrahydrofuran
T=-40 - 0°C; 2 h;
2: 1H-Indole-5-carbaldehyde With sodium hexamethyldisilazane in tetrahydrofuran
T=20°C;
1: in diethyl ether
T=-60°C; Addition;
2: With boron trifluoride diethyl etherate in diethyl ether
T=-60 - 20°C; Substitution; Dimerization;
3: With water in diethyl ether
Hydrolysis; Further stages.;
参考文献
Barluenga, Jose; Rodriguez, Felix; Fananas, Francisco J.
Chemistry - A European Journal, 2000 , vol. 6, # 11 p. 1930 - 1937
in tetrahydrofuran
T=-110°C; 2 h; other substrates; Mechanism;
参考文献
Seyferth, Dietmar; Weinstein, Robert M.; Hui, Richard C.; Wang, Wei-Liang; Archer, Colin M.
Journal of Organic Chemistry, 1992 , vol. 57, # 21 p. 5620 - 5629
Seyferth, Dietmar; Weinstein, Robert M.; Hui, Richard C.; Wang, Wei-Liang; Archer, Colin M.
Journal of Organic Chemistry, 1992 , vol. 57, # 21 p. 5620 - 5629
