Gilman; Esmay
Journal of the American Chemical Society, 1953 , vol. 75, p. 278,280
Full Text Show Details
Truce; Amos
Journal of the American Chemical Society, 1951 , vol. 73, p. 3013,3016
in diethyl ether
T=-78°C; 0.5 h; investigation of reactions with various organolithiums, solvent: diethyl ether, THF, dimethoxyethane, hexane, temperature: -78 deg C or r.t.; Product distributionMechanism;
1: acetoacetic acid methyl ester With sodium hydride in tetrahydrofuran
T=0°C; 0.166667 h;
2: n-butyllithium in tetrahydrofuran; cyclohexane
T=0°C; 0.166667 h;
3: 3-fluoro-1-bromomethylbenzene With hydrogenchloride
more than 3 stages;
参考文献
Chen, Shoujun; Sun, Lijun; McCleary, Joel
Patent: US2003/236302 A1, 2003 ;
Location in patent: Page 11 ;
