copper(l) iodide 1.) ether, THF, n-hexane, -30 deg C, 1 h, 2.) ether, THF, n-hexane, from -70 deg C to RT; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
in hexane reaction of the solid chalcogenide phase with a hexane soln. of n-BuLi;
参考文献
Khudorozhko, G. F.; Asanov, I. P.; Mischenko, A. V.; Mazalov, L. N.; Erenburg, S. B.; et al.
Journal of Solid State Chemistry, 1988 , vol. 74, p. 16 - 20
Kurskii, Yu. A.; Baryshnikov, Yu. N.; Kaloshina, N. N.; Vesnovskaya, G. I.
J. Gen. Chem. USSR (Engl. Transl.), 1981 , vol. 51, # 2 p. 362 - 366,293 - 296
in tetrahydrofuran T=-5°C; 0.0833333 h; various amounts of nBuLi, other iodine compounds, various organolithium reagents; Product distributionMechanism;
in n-heptane T=-20°C; addition of lithium tert- butoxide or lithium trimethylsilanolate; KineticsMechanism;
参考文献
Baryshnikov, Yu. N.; Kurskii, Yu. A.; Kaloshina, N. N.; Vesnovskaya, G. I.
J. Gen. Chem. USSR (Engl. Transl.), 1982 , vol. 52, # 10 p. 2288 - 2292,2037 - 2040
