oxygen; methylene blue T=8°C; 16 h; Irradiationphotoreaction by the action of the sunlight; further temperatures, reaction times, concentrations of reagents, photosensitizers, also with conc. HCl; Product distributionRate constantQuantum yield;
di-tert-butyl peroxide T=140°C; 2 h; relative rates of fragmentation and addition; Rate constantMechanism;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 33, # 10 p. 2109 - 2112
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 10 p. 2310 - 2314
di-tert-butyl peroxide T=140°C; 2 h; relative reactivity of CH and CH2O groups in radical formation; Product distributionMechanism;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 33, # 10 p. 2109 - 2112
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 10 p. 2310 - 2314
